【摘 要】
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The Stokes–Einstein relation D~T/ηand its two variants D~τ?1 and D~T/τfollow a fractional form in super-cooled liquids, where D is the diffusion constant, T th
【机 构】
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Departments of Physics&Key Laboratory of Photonic and Optical Detection in Civil Aviation, Civil Avi
论文部分内容阅读
The Stokes–Einstein relation D~T/ηand its two variants D~τ?1 and D~T/τfollow a fractional form in super-cooled liquids, where D is the diffusion constant, T the temperature,η the shear viscosity, andτ the structural relaxation time. The fractional Stokes–Einstein relation is proposed to result from the dynamic heterogeneity of supercooled liquids. In this work, by performing molecular dynamics simulations, we show that the analogous fractional form also exists in sodium chloride (NaCl) solutions above room temperature. D~τ?1 takes a fractional form within 300–800 K;a crossover is observed in both D~T/τ and D~T/η. Both D~T/τ and D~T/η are valid below the crossover temperature Tx , but take a fractional form for T >Tx . Our results indicate that the fractional Stokes–Einstein relation not only exists in supercooled liquids but also exists in NaCl solutions at high enough temperatures far away from the glass transition point. We propose that D~T/η and its two variants should be critically evaluated to test the validity of the Stokes–Einstein relation.
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