CuCl-catalyzed Oxidative N-Demethylation of Arylamines with tButyl Hydroperoxide

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CuCl-catalyzed oxidative N-demethylation of arylamines proceeded in the presence of tert-butyl hydro-peroxide. The one-electron transfer route of oxidative N-demethylation competed favorably with the H-atom abstraction route.
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