10,9-硼氧杂菲的四配位硼化合物很少见报道。我们曾报道10-羟基-10,9-硼氧杂菲与β-二酮反应可生成两种类型的四配位硼化合物。本文将报道10-羟基-10,9-硼氧杂菲与脂肪族β-氨基醇(氨基乙醇、氨基丁醇、羟乙基乙二胺和二甲胺基乙醇)和喹啉的取代衍生物(8-羟基喹啉、5,7-二溴-8-羟基喹啉和喹哪啶酸)反应,得到7种新的10,9-硼氧杂菲含氮衍生物。其合成路线如下: The tetradentate boron compounds of 10,9-boraxophenanthrene are seldom reported. We have reported that the reaction of 10-hydroxy-10,9-boraxepin with β-diketone produces two types of tetracoordinate boron compounds. In this paper, substituted derivatives of 10-hydroxy-10,9-boraxepine with aliphatic β-amino alcohols (aminoethanol, aminobutanol, hydroxyethylethylenediamine and dimethylaminoethanol) and quinoline (8-hydroxyquinoline, 5,7-dibromo-8-hydroxyquinoline and quinaldic acid) to give seven new 10,9-boroxanthene nitrogen-containing derivatives. The synthetic route is as follows: