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采用接触辉光放电反应器降解罗丹明B,考察降解过程中脱色、矿化以及毒性变化.实验结果表明,Na2SO4为电解质时,降解60 min后,8.0 mg/L罗丹明B脱色率为77.72%,但TOC去除率仅为5.12%,抑制率则从初始27.02%上升至72.86%.Fe2+为0.3 mmol/L时,放电30 min,脱色率接近100%,矿化率为50.12%,抑制率则从60.21%减小到14.70%.NaCl为电解质时,放电30 min,脱色率接近100%,TOC去除率为48.09%,抑制率在前5 min升高然后逐渐降低到3.07%.一定浓度的Fe2+或Cl-不仅能有效加快罗丹明B溶液的脱色率、矿化率,且能降低降解液的毒性.“,”The decolorization,mineralization and toxicity change of Rhodamine B (RB) in aqueous solution with contact glow discharge electrolysis (CGDE) were investigated.With Na2SO4 as the electrolyte,after 60 min CGDE treatment,the decolorization efficiency of 8.0 mg/L RB was 77.72% and the TOC removal was 5.12%.However,the inhibition rate increased from the initial 27.02% to 72.86%.With 0.3 mmol/L Fe2+ in presence of solution,the decolorization efficiency was close to 100% after 30 min treatment and 50.12% of TOC was removed.The inhibition rate decreased from 60.21% to 14.70%.With NaCl as electrolyte,after 30 min treatment,the decolorization efficiency was close to 100% and 48.09% of TOC was removed.The inhibition rate abruptly decreased to 3.07%.The presence of Fe2+ or Cl-not only accelerated the decolorization and mineralization of RB,but also decreased the toxicity of the degradation solution,which provided fundamental data for the practical application.