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利用流动余辉技术,首次研究了Ar(3P2,0)/CO2与CS2的传能反应,证实了CS(A,a)是通过化学反应产生的,并计算了CS(A)的形成速率常数为1.41s×10-12cm3molecule-1s-1.同时对反应中在340~640nm范围内的连续光谱的归属问题进行了讨论,并计算了其形成速率常数为2.91×10-10cm3molecule-1s-1.
The energy transfer reaction between Ar (3P2,0) / CO2 and CS2 was first studied by the flow afterglow technique. It was confirmed that CS (A, a) was produced by chemical reaction and the formation rate constant of CS (A) 1.41s × 10-12cm3molecule-1s-1. At the same time, the assignment of continuum spectra in the range of 340 ~ 640nm was discussed. The formation rate constant was calculated to be 2.91 × 10-10cm3molecule-1s-1.