本文利用柔性的N,N,N′,N′-间-二甲苯二胺四乙酸(H4L)及不同的氮杂环配体如刚性的4-4′-联吡啶(4,4′-bipy)及柔性的间-二(咪唑-1-亚甲基)苯(mbix)构筑了2个新的一维铜配位聚合物{[Cu2L(4,4′-bipy)(H2O)2].2.5H2O}n(1)和{[Cu2L(mbix)(H2O)2].3H2O}n(2),并对其进行了元素分析、红外光谱和X-ray单晶衍射表征。另外利用紫外-可见光谱的方法对2个化合物与H2O2的氧化反应进行了研究,结果表明虽然化合物1和2在高浓度的H2O2条件下均发生了分子断裂,但仍能使配体L4-中二甲苯基联接体C2位置发生羟基化。 In this paper, we use flexible N, N, N ’, N’-m-xylenediaminetetraacetic acid (H4L) and different azole ligands such as rigid 4-4’-bipyridyl (Cu2L (4, 4’-bipy) (H2O) 2]) was synthesized by the same method and flexible mbix. 2.5H2O} n (1) and {[Cu2L (mbix) (H2O) 2] .3H2O} n (2) were synthesized and characterized by elemental analysis, IR and X-ray single crystal diffraction. In addition, UV-Vis spectroscopy was used to study the oxidation of the two compounds with H2O2. The results showed that although the compounds 1 and 2 underwent molecular cleavage under high H2O2 concentration, the L4- Hydroxylation occurs at the xylene linker C2 site.