Synthesis, spectroscopic and electrochemical property of an unsymmetrical porphyrin and its Zn compo

来源 :中国化学快报(英文版) | 被引量 : 0次 | 上传用户:woaiyan0
下载到本地 , 更方便阅读
声明 : 本文档内容版权归属内容提供方 , 如果您对本文有版权争议 , 可与客服联系进行内容授权或下架
论文部分内容阅读
In this article, a new 5-(p-maleicaminophenyl)-10,15,20-triphenylporphyrin (H2P) and relative zinc compound (ZnP) were synthesized and characterized by means of elemental analyses, UV-vis, IR, MS and 1H NMR spectroscopies. Furthermore, we have investigated the fluorescence spectroscopy of these compounds. The oxidation and reduction properties of the compounds were studied by the cyclic voltammetry, the oxidation-reduction potentials were obtained.
其他文献
近几年,随着我国经济的飞速发展,我国的道路以及桥梁建设工程也得到了空前的发展,混凝土施工技术在一定程度上也得到了提高.但是传统的道路以及桥梁工程在施工的过程中依然存
通过测量PC型HgCdTe探测器的动态响应,发现在工作温度(77K)下,激光辐照后,探测器的电导率产生改变(记忆),电阻变化率提高,这种现象在工作温度下能长期保持.当升温(至室温)后,记忆功能消失.本文对这种现
The title compound,[Zn(4-pytpy)(NO3)2] (4-pytpy = 4'-(4-pyridyl)-2,2'∶6',2"-terpyridine) 1,has been synthesized by the solvothermal reaction of Zn(NO3)2·6H2O
Transparent thin films of ZnO have been prepared on ordinary glass substrates by the inorganic sol-gel method using citric acid as chelating agent and zinc nitr
A new metal-organic coordination polymer [Zn2(dpphen)2(H2btec)(btec)0.5]n(dpphen = 4,7-diphenyl-l,10-phenanthroline,H4btec = 1,2,4,5-benzenetetracarboxylic acid
为探究吕家坨井田地质构造格局,根据钻孔勘探资料,采用分形理论和趋势面分析方法,研究了井田7
A novel organophosphorus compound containing the structure of both β-amino acid and B-aminophosphonate is designed and synthesized. Arbuzov reaction with P(OEt
This paper reports the growth,X-ray diffraction and spectroscopy of Nd3+:Sr3Gd2(BO3)4crystal.A Nd3+:Sr3Gd2(BO3)4 crystal with dimensions of φ20 × 45 mm3 has b
The layer-by-layer(LBL)selfassembly of anionic and cationic multi-walled carbon nanotubes(MWNTs)through electrostatic interaction has been carried out to fabric
A new polyacetylene glycoside,(1,3Z,11E)-tridecatriene-7,9-diyne-5-hydroxyl-6-O-β-D-glucopyranoside,was isolated from the rhizomes of Atractylodes lancea(Thunb