论文部分内容阅读
本文研究了由苯甲酰氨产生的［Ｃ_７Ｈ_５Ｏ］~（２＋·）双电荷离子的单分子解离反应及碰撞诱导解离（ＣＩＤ）和电子捕获诱导解离（ＥＣＩＤ）反应，讨论了离子的结构及电荷分离过渡态的结构，该离子主要以保持苯环或苯环上Ｈ迁移到侧链的结构存在。用在碰撞室上加电压的方法，排除了ＣＩＤ和ＥＣＩＤ谱中单分子解离产物的干扰。
In this paper, the single-molecule dissociation and collision-induced dissociation (CID) and electron-capture induced dissociation (ECID) reactions of [C_7H_5O] ~ (2 + Structure and charge separation transition state structure, the ion mainly in the benzene ring or benzene ring to migrate to the side chain structure exists. The voltage applied to the collision cell was used to eliminate the interference of single molecule dissociation products in the CID and ECID spectra.