论文部分内容阅读
本文报导在季铵盐存在下用氢型丝光沸石催化α-蒎烯的水合反应,该反应立体选择性地一步合成了光学活性α-松油醇。作者认为主产物α-松油醇的生成是通过离子对协助碳正离子重排进行的。
This paper reports the hydration of α-pinene catalyzed by hydrogen-type mordenite in the presence of quaternary ammonium salts, which synthesizes the optically active α-terpineol stereoselectively in one step. The author believes that the main product α-terpineol is generated through ion-assisted carbon cations rearrangement.