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研究了四（苄硫基）四硫富瓦烯／硬脂酸（TBT－TTF／SA）（1：1）LB膜、二（亚乙二硫基）四硫富瓦烯／硬脂酸（BEDT－TTF／SA）（1：1）LB膜和四（十六烷硫基）四硫富瓦烯／硬脂酸（THT－TTF／SA）（1：1）LB膜的结构．从X射线衍射结果得到了LB膜的层间距离．X射线衍射图显示了TBT－TTF／SALB膜和BEDT－TTF／SALB膜的层间结构由硬脂酸控制．从偏振红外结果计算出硬脂酸和四硫富瓦烯衍生物在LB膜中的取向角．根据分子取向角确定了LB膜的层间结构．用分子长度和分子取向角得到的层间距离与从X射线衍射得到的层间距离相吻合．
In this paper, LB films of tetrakis (benzylthio) tetrathiafulvalene / stearic acid (TBT-TTF / SA) (1: 1) BEDT-TTF / SA) (1: 1) LB film and tetrakis hexadecylthio tetrathiafulvalene / stearic acid (THT-TTF / SA) The interlayer distance of the LB film was obtained from the X-ray diffraction results. The X-ray diffraction pattern shows that the interlayer structure of TBT-TTF / SALB film and BEDT-TTF / SALB film is controlled by stearic acid. The orientation angles of the stearic acid and tetrathiafulvalene derivatives in the LB film were calculated from the results of the polarization infrared. The interlayer structure of LB film was determined according to the molecular orientation angle. The interlayer distance obtained from the molecular length and molecular orientation coincides with the interlayer distance obtained from X-ray diffraction.