【摘 要】
：
The title compound (C15H13ClN2OS, Mr = 304.9) crystallizes in the triclinic system space group P1, a=7. 984(2), b=9.712(1), c=11. 140(1) A ,α=97.58(1),β=110.
【机 构】
：
Department of Chemistry,Chengdu Institute of Organic Chemistry
论文部分内容阅读
The title compound (C15H13ClN2OS, Mr = 304.9) crystallizes in the triclinic system space group P1, a=7. 984(2), b=9.712(1), c=11. 140(1) A ,α=97.58(1),β=110. 55(1), γ=106. 14(1)°, V=751.2(2)A 3, Z=2, Dc=1. 347g/cm3,μ(MoKα)=0. 389cm-1, F(000)=316. The final R and wR are 0. 0349 and 0.0894 for 2008 observed reflections (I≥2σ(I)), respectively. In the molecule of the title compound , there is an intramolecular hydrogen bond between the amide N and benzyl O atoms , forming a six-membered ring in the central part of molecule. In the crystal, molecules are connected into infinite zigzag chins by N-H…S(-x,-y+1,-z)and weak interaction N-H…O(-x-1,-y-1,-z-1)along the direction[101](a+c).The weak intermolecular interaction Cl…Cl(-x,-y,-z)links the chains into a layer. Between the resulting layers there are mainly van der Waals interactions.
其他文献
应用原子分子反应静力学原理导出LaH分子的电子状态和可能的离解极限,考虑相对论紧致有效势RCEP(RelativisticCompactEffectivePotential)近似下,用QCISD方法计算了LaH分子基
A zirconia-pillared layered lanthanum niobate was prepared by first preswelling layered HLaNb2O7 with n-hexadecylamine(n-C16H33NH2), then further reacting with
为探究吕家坨井田地质构造格局,根据钻孔勘探资料,采用分形理论和趋势面分析方法,研究了井田7
ALM In order to study the association between the null genotypes of GSTM1 and GSTT1 and the genetic susceptibility to hepatocellular carcinoma (HCC).METHODS
A novel highly active Cs-symmetric metallocene catalyst namely: meso-dimethylsilylbis (2,4,6-trimethyl-1-indenyl)zirconium dichloride is presented. The effect o
IntroductionThe carbonylation of alcohols via homogenous catalysis is important in manufacturingacetic acid and higher carboxylic acids and their esters[1 ,2 ]
职业教育是我国教育体系中的重要一环,学生们在接受了完整的职业教育后,就将进入社会,走向工作岗位.在全球经济一体化的今天,职业教育中的英语教学工作重要性日益增加,重要性
（ＣＯ＋Ｃｓ）／Ｒｕ（１０１０）共吸附的体系中，ＣＯ分子由于受Ｃｓ原子强烈影响，分子轨道发生 重新杂化组合．ＣＯ分子原来在清洁 Ｒｕ（１０１０）表面上结合能位于 ７．５ｅＶ处相重叠的５σ和 １π轨道 对应谱峰分裂为两峰，结合能分别位于 ６.３和 ７．８ ｅＶ处．其中
电子束蒸发在硅衬底上的多晶铝膜多孔型阳极氧化得到的多孔列阵排布与体材料单晶 铝氧化结果比较，有序度存在很大差异，导致这种差异的原因，除了氧化时间、应用电压、电解液等 电
Let D = (V,E) be a primitive digraph. The exponent of D, denoted by γ(D), is the least integer k such that for any u, v ∈ V there is a directed walk of length