【摘 要】
：
Cp2Yb·2THF reacts with CpNa in 1:1 molar ratio in THF at 40℃ for 2 h, and the in situ generated anionic divalent complex NaYbCp3(THF)n reacts further with an
【机 构】
：
The Key Laboratory of Organic Synthesis of Jiangsu Province
论文部分内容阅读
Cp2Yb·2THF reacts with CpNa in 1:1 molar ratio in THF at 40℃ for 2 h, and the in situ generated anionic divalent complex NaYbCp3(THF)n reacts further with an excess of CpH at 40℃ for 48 h, after work-up, affording the trivalent anionic ytterbium complex [Na(THF)2(μ2-η5-Cp)(η5,η5,η1- Cp3Yb)(THF)]n(1) by oxidation reaction of Cp2Yb with CpH. Crystal structure determination reveals that complex 1 has one-dimension polymeric chains of distinct Na(THF)2(μ2-η5-Cp)(η5,η5,η1- Cp3Yb)(THF)units, which were formed by the coordination of the bridging Cp ligand with Cp3Yb·THF and Na(THF)2 in η5,η5 mode via self-assembly.
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