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分别以10-十一碳烯酸和丙炔醇为起始原料,通过炔化物路线(第1个中间体是10-十一碳炔醇-1(5),第2个中间体是10-十六碳炔醇-1(8))分别立体选择性合成了桃柱螟性信息素成分(E)-10-十六碳烯醛(1)和(Z)-10-十六碳烯醛(2)。
Respectively, 10-undecylenic acid and propargyl alcohol as the starting material, through the acetyl route (the first intermediate is 10-undecylenyl alcohol -1 (5), the second intermediate is 10- (E) -10-hexadecenal (1) and (Z) -10-hexadecenal (2).