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A kind of low surface energy fluorocarbon coatings from the synthesized fluoro-acrylic resin was developed.The molecule orientation principle of nonpolar and polar functional groups in the coatings was analyzed. The contact angles of pure water drops on the surfaces of various fluoro-monomer homopolymers and interpolymers were measured. The relation of coatings fluoro-content with the surface energy was determined. The distribution of fluoric functional groups in the coatings was investigated. The test results show that though the total content of fluor of the fluorocarbon coatings is relative few, their surface energy is really low due to the enrichment of fluoro-chains on the surfaces.