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采用蒋洪圻和徐光宪的处理方法,用极谱法研究了亚铊离子和乙酸根的络合,得到TlAc和Tl(Ac)_2~-的逐级稳定常数分别为:K_1=0.0661,K_2=0.178(25℃,μ=3.00,用NaClO_4维持).
Using the method of Jiang Hongtao and Xu Guangxian, the complexation of the thallium ions and acetate was studied by polarographic method. The steady-state constants of TlAc and Tl (Ac) 2 ~ were K_1 = 0.0661 and K_2 = 0.178 25 ° C, μ = 3.00, maintained with NaClO_4).