Synthesis, crystal structures, and magnetic properties of two three-dimensional octacyanotungstate(I

来源 :中国科学：化学英文版 | 被引量 : 0次 | 上传用户：jackzeng6699

【摘要】

：

The reaction of [HN(n-C4H9)3]3[WV(CN)8]·4H2O, 4,4′-bipyridine dioxide(4,4′-dpdo), and MnCl2·4H2O or CuCl2·2H2O gives two new three-dimensional

【作者】

：

Mei Yuan (1) Song Gao (1)

【机构】

：

1.BeijingNationalLaboratoryforMolecularSciences

【出处】

：

中国科学：化学英文版

【发表日期】

：

2009年3期

【关键词】

：

octacyanometalates 4 4′-bipyridine dioxide COORDINATION polymer CAVITIES MAGNETI

【基金项目】

：

Supported by the National Natural Science Foundation of China (Nos. 20221101, 20490210, and 20701039),the National Basic Research Program of China (No. 2006CB601102)

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The reaction of [HN(n-C4H9)3]3[WV(CN)8]·4H2O, 4,4′-bipyridine dioxide(4,4′-dpdo), and MnCl2·4H2O or CuCl2·2H2O gives two new three-dimensional octacyanometalate-based bimetallic assemblies, {[Mn2 (4,4′-dpdo)(H2O)4] [WIV(CN)8]}·6H2O (1)

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Synthesis, crystal structures, and magnetic properties of two three-dimensional octacyanotungstate(I

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