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固相配位化学研究配位化合物在固态条件下的反应及性质。有关室温条件下的固相配位反应的报导很少。本文用XRD方法研究Cu(Ac)_2·H_2O与甘氨酸在室温条件下的固相配位化学反应,探讨碱对反应产物的影响。 试剂均为分析纯,cis-trans-[Cu(gly)_2)·H_2O按文献[2]合成。实验均在Ar气氛下进行。XRD图用岛津XD-3A型X-射线衍射仪测取,铜靶,扫描速度4°/min。定量分析根据下武:
Solid - State Coordination Chemistry Study on the Reaction and Properties of Coordination Compounds under Solid State Conditions. There are few reports about the solid phase coordination reaction at room temperature. In this paper, the solid-phase coordination reaction between Cu (Ac) 2 · H 2 O and glycine at room temperature was investigated by XRD and the effect of alkali on the reaction products was investigated. The reagents were of analytical grade and cis-trans- [Cu (gly) _2) · H_2O was synthesized according to [2]. Experiments were carried out in Ar atmosphere. XRD patterns were measured with a Shimadzu XD-3A X-ray diffractometer, copper target, scanning speed 4 ° / min. Quantitative analysis based on the next martial: