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测定了333～363K范围内Ni[(C_8H_(17)O)_2PS_2]_2与1,4-二氧六环加合反应的平衡常数,采用最小二乘法求得反应的ΔH和ΔS.加合反应的平衡常数可以用下列经验公式描述: lgK=-1.5957+537.54/T
The equilibrium constants of the addition reaction of Ni [(C_8H_ (17) O) _2PS_2] _2 with 1,4-dioxane in the range of 333-363 K were determined, and the ΔH and ΔS of the reaction were determined by the least squares method. The equilibrium constant can be described by the following empirical formula: lgK = -1.5957 + 537.54 / T