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层格状硅酸盐的固体酸度通过用钛离子交换层间阳离子而得以显著提高,钛离子交换的蒙脱上可选择性催化甲醇脱氢生成低碳烯烃。在作者广泛研究中发现,新型的甲醇转化可生成各种含氧化合物。杂离子交换的氟代四硅云母(TSM)和Ti-
The solid acidity of phyllosilicates is significantly enhanced by exchanging interlayer cations with titanium ions, which can be catalytically dehydrogenated to produce lower olefins by selective oxidation of titanium ions. In the author’s extensive study found that a new type of methanol conversion can generate a variety of oxygenated compounds. Heteroion-exchanged fluorosilicone mica (TSM) and Ti-