利用中性伯胺 (十二胺 )作模板剂 ,合成了过渡金属Cu、　Ti、　Co、或Fe取代的HMS中孔材料 .XRD和FT IR表征表明 ,Cu和Ti能有效地嵌入HMS骨架壁中而不会造成其中孔有序度的下降 ;而Co和Fe的嵌入会明显降低表面活性剂的模板组装作用 ,从而造成中孔结晶有序度的显著下降 .催化实验结果表明 :Cu HMS和Fe Silica是苯酚羟基化的有效催化剂 ,而Ti HMS则是苯乙烯环氧化的有效催化剂 HMS mesoporous materials with transition metals Cu, Ti, Co, or Fe were synthesized by using neutral primary amine (dodecylamine) as template.The XRD and FT IR characterization indicated that Cu and Ti could be efficiently embedded in the HMS framework wall While the decrease of order degree of mesopores will not result in the decrease of the degree of order of mesopores. However, the intercalation of Co and Fe significantly reduces the template assembly of the surfactant, resulting in a significant decrease in the orderliness of mesopore crystallization. Fe Silica is a potent catalyst for the hydroxylation of phenol while Ti HMS is a potent catalyst for the epoxidation of styrene