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The reaction of triphenylphosphine with AgNO3 yielded an unusual nitrate anion bridging one-dimensional infinite chain [Ag(PPh3)NO3]u001f in which the silver(I) atom is three-coordinated by one P atom of triphenylphosphine and two O atoms of two bridging nitrate anions to form a scalene triangle. The complex [Ag(PPh3)NO3]u001f crystallizes in the monoclinic system, space group P21/c with a = 10.281(2), b = 18.596(5), c = 9.180(2) , = 90.60(1), V = 1755.1(7) 3, Z = 4, Mr = 432.15, Dc = 1.635 g/cm3, F(000) = 864 and = 1.254 mm-1. The final R = 0.0606 and wR = 0.1400 for 2188 observed reflections with I > 2(I) out of 3057 unique ones (Rint = 0.0539). IR and elemental analysis of the complex are characterized.
The reaction of triphenylphosphine with AgNO3 yielded an unusual nitrate anion bridging one-dimensional infinite chain [Ag (PPh3) NO3] u001f in which the silver (I) atom is three-coordinated by one P atom of triphenylphosphine and two O atoms of two The complex [Ag (PPh3) NO3] u001f crystallizes in the monoclinic system with space group P21 / c with a = 10.281 (2), b = 18.596 (5), c = 9.180 2 = 90.60 (1) V = 1755.1 (7) 3 Z = 4 Mr = 432.15 Dc = 1.635 g / cm3 F (000) = 864 and = 1.254 mm-1 The final R = 0.0606 and wR = 0.1400 for 2188 observed reflections with I> 2 (I) out of 3057 unique ones (Rint = 0.0539). IR and elemental analysis of the complex are characterized.