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The electrochemistry of (TPP)Co in the presence of pyridine was investigated indichloroethane solution by cyclic voltammetry. With the addition of pyridine to the solution, thereduction Peaks of the axial complex compounds, (TPP)Co(III)(Py) and (TPP)Co(III)(Py)2 wereobserved. It was found that the reduchon peak of Co(II)/Co(I) shifted to about -1 .20V (SCE) with theincrease of added Pyridine. The new reduction peak may be attributed to the direct reduction of theaxially complex (TPP)Co(II)(Py)
The electrochemistry of (TPP) Co in the presence of pyridine was investigated for the addition of pyridine to the solution, the reduction Peaks of the axial complex compounds, (TPP) Co (III) (Py) and (TPP It was found that the reduchon peak of Co (II) / Co (I) shifted to about -1 .20V (SCE) with theincrease of added Pyridine. The new reduction peak may be attributed to the direct reduction of the axially complex (TPP) Co (II) (Py)