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以磺胺喹噁啉为配体合成了2种锌的配合物[Zn(L)2(phen)]·H2O(1)和{[Zn(L)2(bpy)]·2Et OH}n(2)(L=磺胺喹噁啉,phen=菲咯啉,bpy=4,4′-联吡啶)并对其进行了单晶X-射线衍射,粉末X-射线衍射,热重,元素分析,红外光谱,紫外光谱和荧光光谱测定。单晶X-射线分析表明化合物1是单核结构,属单斜晶系,P21/c空间群。化合物2是一维结构,属单斜晶系,C2/c空间群。热分析表明化合物1和2都有很高的热稳定性。
Two complexes of zinc [Zn (L) 2 (phen)] · H2O (1) and {[Zn (L) 2 (bpy)] · 2EtOH} n (2 ) (L = sulfaquinoxaline, phen = phenanthroline, bpy = 4,4’-dipyridyl) and subjected to single crystal X-ray diffraction, powder X-ray diffraction, thermogravimetry, elemental analysis, infrared Spectroscopy, UV and fluorescence spectrometry. Single crystal X-ray analysis showed that compound 1 is a mononuclear structure and belongs to the monoclinic space group P21 / c. Compound 2 is a one-dimensional structure, which belongs to monoclinic system, C2 / c space group. Thermal analysis showed that both compounds 1 and 2 have very high thermal stability.