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氟丙酮(FCH_2COCH_3)是最简单的氟代酮。早在1933年,R(?)y及其同工作者,就报导了由碘丙酮(ICH_2COCH_3)与无水氟化铊(TIF)作用,可以制得氟丙酮,并且指出氯丙酮(ClCH_2COCH_3)与无水氟化铊没有反应。随后,R(?)y等更详细地报导了由溴丙酮(BrCH_2COCH_3)与氟化铊在乙醚中长时回流制备氟丙酮的方法。后来,在1941年,Fuku-hara等也从丙酮与元素氟直接氟化后的混合产物中,分离出了氟丙酮。自此以后的十
Fluoroacetone (FCH 2 COCH 3) is the simplest fluoroketone. As early as 1933, R? Y and colleagues reported that fluoroacetone can be obtained from the action of iodoacetone (ICH_2COCH_3) and anhydrous thallium fluoride (TIF), and pointed out that chloroacetone (ClCH_2COCH_3) Thallium fluoride anhydrous did not react. Subsequently, R (?) Y and so on in more detail reported by bromoacetone (BrCH_2COCH_3) and thallium fluoride in ether long-time reflux preparation of fluoroacetone. Later, in 1941, Fuku-hara et al. Also isolated fluoroacetone from the mixed product of the direct fluorination of acetone with elemental fluorine. Since then ten