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The title complex [ZnⅡ8(4-APha)8(CH3COO)8(CH3CH2OH)2]n(1, 4-APha = 4-aminophenylhydroxamic acid) has been prepared under solvothermal conditions. It has been characterized by X-ray single-crystal diffraction, IR and elemental analysis. The crystal belongs to the monoclinic system, space group C2/c with a = 39.074(4), b = 9.9645(8), c = 38.846(3) A, β = 136.438 o, V = 10423.1(14) A3, C84H118N16O39Zn8, Mr = 2498.90, Z = 4, Dc = 1.592 g/cm3, μ = 1.900 mm-1, F(000) = 5144, the final R = 0.1036 and wR = 0.2953. This complex possesses a 3-D structure which is constructed from 1-D chain motifs linked by the 4-APha- ligands. The luminescent property of the title complex has been investigated.
The title complex [ZnⅡ8 (4-APha) 8 (CH3COO) 8 (CH3CH2OH) 2] n (1,4-APha = 4- aminophenylhydroxamic acid) has been characterized by X-ray single- The crystal belongs to the monoclinic system, space group C2 / c with a = 39.074 (4), b = 9.9645 (8), c = 38.846 (3) A, β = 136.438 °, V = 10423.1 (14) A3, C84H118N16O39Zn8, Mr = 2498.90, Z = 4, Dc = 1.592 g / cm3, μ = 1.900 mm- 1, F (000) = 5144, the final R = 0.1036 and wR = 0.2953. This complex possesses a 3-D structure which is constructed from 1-D chain motifs linked by the 4-APha ligands. The luminescent property of the title complex has been investigated.