By using a new reaction model for light nuclei, the double-differential cross section of n+14N reactions at En = 14.2 MeV has been analyzed. In the case of n+14N reactions, the reaction mechanism is very complex, there are over one hundred opened partial reaction channels even at incident energy En = 14.2 MeV. In this paper the opened reaction channels are listed in detail. With LUNF code the model calculation is performed to analyze the doubledifferential cross sections of total outgoing neutron. The calculated results agree fairly with the experimental data. The results indicate that the pre-equilibrium mechanism dominates the whole reaction processes, and the recoil effect in light nuclear reactions is essentially important. 5He emission has been considered, but it is only a small contribution to the double-differential cross section at incident energy En = 14.2 MeV.