论文部分内容阅读
本文研究了金属簇烷川九羰基三钴络合物YCCo_3(CO)_9的羰化活性。同系物HCCo_3(CO)_9、PhCCo_3(CO)_9、ClCCo_3(CO)_9和EtOOCCCo_3(CO)_9在较缓和条件130℃,40公斤/厘米~2,H_2/CO=2时已烯—1羰化克分子转化率95％以上。该类簇络合物还有加氢和双键异构化作用。
In this paper, the carbonylation activity of the metal cluster alkanenacarbonyltrit Cobalt complex YCCo_3 (CO) _9 was studied. The homologues HCCo_3 (CO) _9, PhCCo_3 (CO) _9, ClCCo_3 (CO) _9 and EtOOCCCo_3 (CO) _9 were more stable under the mild conditions of 130 ℃, 40 kg / cm ~ 2 and H_2 / CO = Chemical conversion rate of 95% or more. Such cluster complexes also hydrogenation and double bond isomerization.