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锆氢试剂Cp2Zr(H)Cl、Cp2ZrH2可在温和条件下使直链或支链硫酸发生脱硫反应,生成相应的烷烃,使硫脲发生脱硫反应,生成氨和氢氰酸,并分别得到两种锆的硫桥络合物(Cp2ZrCl)2S1和(Cp2ZrS)22。而锆氢试剂与硫醚不能发生此类脱硫反应。
Zirconium hydrogen reagents Cp2Zr (H) Cl, Cp2ZrH2 can make the straight chain or branched sulfuric acid desulfurization reaction under mild conditions to generate the corresponding alkanes, thiourea desulfurization reaction to generate ammonia and hydrocyanic acid, and were obtained in two Zirconium sulfur bridge complex (Cp2ZrCl) 2S1 and (Cp2ZrS) 22. The zirconium hydrogen reagent and sulfide can not occur such desulfurization reaction.