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The binuclear complex [Ag2(m-Ph2PNHPPh2)3](ClO4)2CH2Cl2CH3OH (Ph2PNHP- Ph2 = bis(diphenylphosphino)amine) was prepared from the reaction of AgClO4 with bis- (diphenylphosphino)amine in equimolar ratio through self-assembly. The coordination cation affords a triply-bridging [Ag2L3]-type coordination moiety. The silver atom is in a trigonal planar environment with P3 coordination chromophore. The complex (C74H69Cl4N3O9P6Ag2) crystallizes in monoclinic, space group Cc with a = 18.3738(1), b = 20.0207(4), c = 20.5422(4) ? b = 95.829(1), V = 7517.5(2) 3, Z = 4, Mr = 1687.68, Dc = 1.491 g/cm3, F(000) = 3432, m = 0.848 mm-1, the final R = 0.0460 and wR = 0.0935 for 7005 observed reflections with I > 2s(I).
The binuclear complex [Ag2 (m-Ph2PNHPPh2) 3] (ClO4) 2CH2Cl2CH3OH (Ph2PNHP- Ph2 = bis (diphenylphosphino) amine) was prepared from the reaction of AgClO4 with bis- (diphenylphosphino) amine in equimolar ratio through self- The complex (C74H69Cl4N3O9P6Ag2) crystallizes in monoclinic space group Cc with a = 18.3738 (1), b = 20.0207 (4), c = 20.5422 (4)? B = 95.829 (1), V = 7517.5 (2) 3, Z = 4, Mr = 1687.68, Dc = 1.491 g / cm3, m = 0.848 mm-1, the final R = 0.0460 and wR = 0.0935 for 7005 observed reflections with I> 2s (I).