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A chemical reaction taking place in a calorimeter is called a thermokinetic system.The recording curve of its temperature during the reaction is called a thermogram.It is very interesting to study the reaction kinetics from.its thermogram but the theory and methods of thermokinetics have not been developed into perfection yet.In this article,the thermokinetic equations of a reacting system are derived in the light of nonequilibrium thermodynamics.And the analytical expression of a thermogram can be derived from the thermokinetic equations.On this theoretical basis,a new research method in thermokinetics has been suggested
A chemical reaction taking place in a calorimeter is called a thermokinetic system. It is very interesting to study the reaction kinetics from.its thermogram but the theory and methods of thermokinetics have not. has developed into perfection yet. In this article, the thermokinetic equations of a reacting system are derived in the light of nonequilibrium thermodynamics. And the analytical expression of a thermogram can be derived from the thermokinetic equations. On this theoretical basis, a new research method in thermokinetics has been suggested