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研究了在Mn(Ⅱ)存在下,我们合成的新试剂二安替比林-(间-乙氧基)-苯基甲烷(DAmEM)与Ce(Ⅳ)生成的橙黄色化合物.该化合物最大吸收位于480nm,表现摩尔吸收系数ε=1.9×10~4L·mol-1cm-1,化合物至少可以稳定8h.服从比尔定律范围为 4~300θg/L,用于镁合金中痕量铈的测定,结果满意.
The orange-yellow compounds of diamtepirin- (m-ethoxy) -phenylmethane (DAmEM) and Ce (Ⅳ) were synthesized in the presence of Mn (Ⅱ) The maximum absorption of the compound at 480nm, showing the molar absorption coefficient ε = 1.9 × 10 ~ 4L · mol-1cm-1, the compound can be stable at least 8h. Obedience Beer’s law range of 4 ~ 300θg / L, for the determination of trace cerium in magnesium alloy, the results are satisfactory.