Synthesis of methyl methacrylate star-branched polymer with divinylbenzene as a linking agent via co

来源 :Chinese Chemical Letters | 被引量 : 0次 | 上传用户:wwbywbytc
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HTEMPO-functionalized central cores were formed with divinylbenzene in ’’core first’’ method,and the four or five arms star polymers were built via controlled/living free radical photopolymerization.The four arms star polymers were also prepared with controlled/living free radical photopolymerization in ’’arm first’’ method.The resulting polymers had been confirmed by GPC and 1 H NMR.It showed that the star polymers had low polydispersities and molecular weight(M n) with the 85,000-560,000 g/mol range. HTEMPO-functionalized central cores were formed with divinylbenzene in ’’ core first ’’ method, and the four or five arms star polymers were built via controlled / living free radical photopolymerization. The four arms star polymers were also prepared with controlled / living free radical photopolymerization in ’arm first’ method. The polymer had been confirmed by GPC and 1 H NMR. It showed that the star polymers had low polydispersities and molecular weight (M n) with the 85,000-560,000 g / mol range.
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