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稀土离子存在于许多磁性材料中,但至今稀土双核配合物的合成及磁性研究很少,建立磁性-结构间的关系对新型分子磁性材料的设计有重要意义。稀土双核配合物的磁性研究也为研究f轨道参与磁相互作用提供第一手材料。我们曾合成了一系列以氯冉酸二价阴离子为桥联配体的过渡金属双核配合物,本文合
Rare earth ions exist in many magnetic materials, but so far rare earth binuclear complex synthesis and magnetic research, the establishment of magnetic - the relationship between the structure of the new molecular magnetic material design is of great significance. The magnetic study of the rare-earth dinuclear complex also provides the first-hand material for the study of f-orbital participation in magnetic interaction. We have synthesized a series of chromate acid dianion as a bridging ligand transition metal binuclear complex, this article