论文部分内容阅读
本文作者制得的单品经分析证明是由质子化大环LH_4~(+4)阳离子、Co(NCS)_6~(-4)阴离子、一分子Co(No_3)_2和4分子H_2O组成,还证明质子化大环L以船式构象存在,为研究超分子配合物的催化机理提供了结构依据。本实验还发现六异硫氰根合钴(Ⅱ)配阴离子能稳定存在。
The single product obtained by the author is proved by the analysis of the protonated macrocycle LH_4 ~ (+4) cation, Co (NCS) _6 ~ (-4) anion, a molecule Co (No_3) _2 and 4 molecules H_2O It is proved that the protonated macrocycle L exists in a shiplike conformation, which provides a structural basis for the study of the catalysis mechanism of supramolecular complexes. The experiment also found that six isothiocyanatobis (Ⅱ) anions with a stable presence.