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本文报道了某些稠环化合物的X射线光电子能谱(XPS)振起伴峰(Shake-up Satellite Peaks)及其HMO计算结果。HMO计算的振起伴峰间距及其振起几率与实验符合较好,同时发现受激原子的振起几率大小和该原子的自由价大小有相同顺序,并建立了受激原子振起几率与化学活性间的关系。
In this paper, X-ray photoelectron spectroscopy (XPS) oscillation peaks of certain fused ring compounds and their HMO calculations have been reported. HMO calculated vibration with the peak spacing and the probability of vibration and the experiment coincides with the good, and found that the excited atoms of the probability of vibration and the free valence of the size of the same order, and established the excited atomic vibration probability and The relationship between chemical activity.