利用连续式膜气液接触器制备纳米CaCO_3:粒子形貌和膜污染(英文)

来源 :Chinese Journal of Chemical Engineering | 被引量 : 0次 | 上传用户:l_zhanghk
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Nanosized calcium carbonate particles were prepared with a continuous gas-liquid membrane contactor. The effects of Ca(OH)2 concentration, CO2 pressure and liquid flow velocity on the particles morphology, pressure drop and membrane fouling were studied. With rising Ca(OH)2 concentrations, the average size of the particles increased. The effects of Ca(OH)2 concentration and CO2 pressure on particles were not apparent under the experimental conditions. When the Ca(OH)2 concentration and liquid flow velocity were high, or the CO2 pressure was low, the fouling on the membrane external surface at the contactor entrance was serious due to liquid leakage, whereas the fouling was slight at exit. The fouling on the membrane inner-surface at entrance was apparent due to adsorption of raw materials. The membrane can be recovered by washing with dilute hydrochloric acid and reused for at least 6 times without performance deterioration. Nanosized calcium carbonate particles were prepared with a continuous gas-liquid membrane contactor. The effects of Ca (OH) 2 concentration, CO2 pressure and liquid flow velocity on the particle morphology, pressure drop and membrane fouling were studied. 2 concentrations, the average size of the particles increased. The effects of Ca (OH) 2 concentration and CO2 pressure on particles were not apparent under the experimental conditions. When the Ca (OH) 2 concentration and liquid flow velocity were high, or the CO2 pressure was low, the fouling on the membrane external surface at the contactor entrance was serious due to liquid leakage, while the fouling was slight at exit. The fouling on the membrane inner-surface at entrance was apparent due to adsorption of raw materials. The membrane can be recovered by washing with dilute hydrochloric acid and reused for at least 6 times without performance deterioration.
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