110keV铁离子束辐照L(+)-半胱氨酸的分子改性研究

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用110keV Fe离子注入L(+)-半胱氨酸薄膜样品,然后通过傅里叶变换红外光谱、紫外-可见光谱和核磁共振氢谱分析表明,L(+)-半胱氨酸在接受Fe离子束辐照后受到了严重损伤,在样品中产生了新的分子基团. ESR波谱分析表明在辐照产物中存在一种长寿命自由基. ESI质谱分析进一步支持了低能离子束辐照所致生物分子改性的发生.
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