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研究了VUV(真空紫外)光直接光CVD(化学汽相淀积)SiO2/Si界面微结构缺陷与衬底温度(Ts)的关系。实验结果表明:在32℃~180℃的温度范围内,与Si-O-Si伸缩模相对应的IR峰位随Ts的降低从1060cm-1增加至1080cm-1。固定氧化物电荷密度(ΔNot)在Ts>120℃后,呈正电性,与位于3.10eV的氧空位缺陷相关;在Ts<100℃一侧,呈负电性,与2.84eV能级位置的过剩氧缺陷相关;而在100℃~120℃间,ΔNot具有极小值,其大小约在1010cm-2数量级。
The relationship between microstructure defects and substrate temperature (Ts) at VUV (vacuum ultraviolet) light direct optical CVD (chemical vapor deposition) interface was investigated. The experimental results show that the IR peak corresponding to Si-O-Si telescopic mode increases from 1060cm-1 to 1080cm-1 with the decrease of Ts within the temperature range of 32 ℃ ~ 180 ℃. The fixed oxide charge density (ΔNot) is positively charged at Ts> 120 ° C, correlates with an oxygen vacancy defect at 3.10 eV, negative at Ts <100 ° C, and negatively charged at 2.84 eV Excess oxygen deficiency related; and in 100 ℃ ~ 120 ℃, ΔNot has a minimum, the size of about 1010cm-2 in the order of magnitude.