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A mononuclear complex, cis-1,10-phenanthroline-palladium(Ⅱ)(THF)2]dinitrate (THF = tetrahydrofuran) [Pd(C10H8N2)(C4H8O)2](NO3)2 1, has been prepared and structurally characterized by single-crystal X-ray diffraction. The crystal belongs to monoclinic system, space group P21/c with a = 7.881(1), b = 27.371(3), c = 10.178(1) ? ?= 103.313(3)? V = 2136.5(4) 3, Mr = 554.83, Dc = 1.725 g/cm3, Z = 4, F(000) = 1128 and (MoK) = 0.926 mm-1. The structure was refined to R = 0.0678 and wR = 0.1651 for 1687 observed reflections with I > 2(I). It is revealed that the central Pd(Ⅱ) ion in the title complex is bonded to two THF and two phenanthroline molecules in a cis-configuration to form the coordination geometry, deviating slightly from the square plane.
A mononuclear complex, cis-1,10-phenanthroline-palladium (II) (THF) 2] dinitrate (THF = tetrahydrofuran) [Pd (C10H8N2) (C4H8O) 2] (NO3) 2 1, has been prepared and structurally characterized by The crystal belongs to monoclinic system, space group P21 / c with a = 7.881 (1), b = 27.371 (3), c = 10.178 (1) = 2136.5 (4) 3, Mr = 554.83, Dc = 1.725 g / cm3, Z = 4, F (000) = 1128 and (MoK) = 0.926 mm- 1. The structure was refined to R = 0.0678 and wR = 0.1651 for is 1687 observed reflections with I> 2 (I). It is revealed that the central Pd (II) ion in the title complex is bonded to two THF and two phenanthroline molecules in a cis-configuration to form the coordination geometry, deviating slightly from the square plane.