Angew.Chem.Int.Ed.2013,52,10056~10059环己二烯酮类化合物是有机合成中一类重要的合成中间体.通过去芳构化反应,可以实现直接由酚类化合物来构建这类骨架.然而,由于酚氧的醚化反应和苯环傅-克烷基化反应的竞争,实现酚类化合物的高化学选择性和立体选择性的去芳构化反应非常有挑战性.目前文献上报道的对酚类化合物的直接催化去芳构化反应主要集中在氧化条 Angew.Chem.Int.Ed.2013,52,10056 ~ 10059 Cyclohexadienones are an important class of synthetic intermediates in organic synthesis, which can be directly constructed from phenolic compounds by dearomatization However, due to the competition between the etherification of phenolic oxygen and the Friedel-Crafts alkylation of benzene rings, it is very challenging to achieve the highly chemical and stereoselective de-aromatization of phenolic compounds. Currently reported in the literature on the direct catalytic de-aromatization of phenolic compounds are mainly concentrated in the oxidation of