论文部分内容阅读
合成了非对称型合μ-β-酯乙基的12个新铁硫原子簇络合物(H-RS)·(μ-P′OCCH_2CH_2S)Fe_2(CO)_6。此外还根据硫桥上所连基因,尤其是乙撑基—CH_2CH_2—的化学位移和积分值,进一步确定了某些络合物的构象休种类及比例。并对反应的某些特点和机理进行了初步讨论。
Twelve new iron sulfur cluster complexes (H-RS) · (μ-P’OCCH_2CH_2S) Fe_2 (CO) _6 with asymmetric μ-β-ester ethyl groups were synthesized. In addition, according to the sulfur bridge connected to the gene, especially ethylene -CH2CH2- chemical shifts and integral values to further determine the conformation of certain complexes of the rest species and proportion. And some characteristics and mechanism of the reaction were discussed preliminarily.