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在已有工作基础上,本文研究了金属卟啉锰(Ⅳ),铁(Ⅲ)和钴(Ⅲ)配合物电催化氧产生超氧离子与2.4—二硝基氯苯进行亲核取代反应的动力学,从而进一步深化了对它的认识。实验方法试剂和仪器:金属卟啉按文献合成,经进一步过柱提纯、紫外光谱和元素分析结果均
Based on the existing work, this paper studied the nucleophilic substitution reaction of superoxide ion with 2.4-dinitrochlorobenzene by the electrocatalytic oxygenation of manganese (Ⅳ), iron (Ⅲ) and cobalt (Ⅲ) complexes of metalloporphyrin Dynamics, which further deepen its understanding. Experimental Methods Reagents and Instruments: Metalloporphyrins were synthesized according to the literature and further purified by column chromatography. The UV spectra and elemental analysis results