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实验研究了CeO2 ·nH2O的表面特性,测定了CeO2·0.61H2O的表面电荷密度.依据溶液配位化学模型,求取了CeO2·0.61H2O颗粒表面配合反应的基本参数,并采用两种方法计算了其与F- 的表面配合稳定常数.
The surface properties of CeO2 · nH2O were investigated experimentally and the surface charge density of CeO2 · 0.61H2O was measured. According to the solution coordination chemistry model, the basic parameters of the coordination reaction on the surface of CeO2 · 0.61H2O particles were obtained. The stability constants of the coordination with F- were calculated by two methods.