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多年来,对于金属物性变化的解释及其表明方式,除众所周知的《元素周期表》法外,曾从不同角度提出过很多方法和经验公式,Wigner、Seitz从电子运动的Schr?dinger方程直接求解计算了碱金属的内聚能,Mott、Slater等用能带模型解释金属的电导及磁性,Jones用电子浓度阐明了金属的晶体结构,以及前人所建立的有关金属单项物性的经验方程式等等。1974年,Grimvall又从Debye温度观点提出与金属物性相关联的问题,1976年,CaMCOHOB等又从电子定位的角度解释金属的许多物性。
Over the years, many methods and empirical formulas have been proposed from different perspectives in addition to the well-known “periodic table” method for the explanation of metal physical changes and their way of expression. Wigner and Seitz solve directly from the Schr? Dinger equation of electron motion Calculating the cohesive energy of alkali metals, Mott, Slater et al. Used the band model to explain the conductance and magnetism of metals. Jones used the electron concentration to elucidate the crystal structure of metals and the empirical equations established by previous researchers about the properties of metals . In 1974, Grimvall again raised the issue of metal physical properties from the Debye temperature perspective. In 1976, CaMCOHOB explained many properties of metals from the perspective of electron localization.