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Organo lanthanide complex (C 5Me 5)NdCl 2·LiCl has been found to be an efficient catalyst for the hydrogenation of nanometric magnesium powder. This magnesium powder was generated by the thermal decomposition of magnesium anthracene in THF at 90~150 ℃ under vacuum. Suitable temperatures for the catalytic hydrogenation of nanometric magnesium powder are between 150~185 ℃ which are much lower than that of the nanometric magnesium powder without catalyst.