含氟磺酰胺可经由含氟磺酰卤或含氟磺酸酐与胺或胺的金属盐反应,或通过含氟横酰胺钠盐与卤代烷反应获得。N-芳基取代的简单含氟横酰胺类化合物可由三氟甲基磺酰氟合成,而聚含氟磺酰胺类化合物的合成则迄今未见报导,本文介绍由含氟磺酰氟I(CF_2)_mO(CF_2)SO_2F合成一系列新 The fluorinated sulfonamide can be obtained by reacting a fluorosulfonyl halide or a fluorosulfonic anhydride with a metal salt of an amine or an amine or by reacting a fluorine-containing hydroxamide with an alkyl halide. Synthesis of N-aryl-substituted simple fluorine-containing transamides can be synthesized from trifluoromethanesulfonyl fluoride. However, the synthesis of polyfluorinated sulfonamides has not been reported until now. In this paper, ) _mO (CF_2) SO_2F Synthesis A series of new