A thermodynamic approach to assess glass-forming ability of bulk metallic glasses

来源 :中国有色金属学报(英文版) | 被引量 : 0次 | 上传用户:dingdang19822003
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According to the Gibbs free energy difference between liquid and crystal, a thermodynamic glass-forming ability(GFA) parameter related to characteristic temperatures, onset crystallization temperature(T_x) and liquidus temperature(T_l), was proposed for evaluating the GFA of bulk metallic glasses(BMGs). The new parameter defined as ω=T_l(T_l+T_x)/(T_x(T_l-T_x)) has good correlation with the critical section thickness(Zc) of Ca-Mg-Cu BMGs. Being verified by the glasses data, including oxide glasses, which were used to validate the former GFA parameters, ω is one of the most reliable and applicable GFA parameters among Trg (=T_g/T_l), γ(=T_x/(T_l+T_g)), α (=T_x/T_l), δ (=T_x/(_Tl-T_g), and so on. Finally, predicting GFA of Cu-Ag-Zr-Ti and Cu-Zr-Ti-Al BMGs using ω was compared with the experimental results.
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