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含硫四氮杂卟啉过渡金属配合物具有比金属卟啉、金属酞菁更为优异的光电功能和催化特性,故近十多年来颇受重视。我们对该类金属配合物和自由配体的合成、性质及其光-光、光-电转换,电化学、光电化学催化,光敏和气敏等功能正进行深入的研究。本文简要报道标题化合物的合成、表征和电子吸收光谱、发射光谱及顺磁共振波谱。
Sulfur tetraazaporphyrazine transition metal complexes with more than the metal porphyrin, metal phthalocyanine more excellent optoelectronic function and catalytic properties, it has been valued for more than a decade. We study the synthesis and properties of these metal complexes and free ligands and their functions such as photo-light, photo-electricity conversion, electrochemistry, photoelectrochemical catalysis, photosensitivity and gas sensitivity. This article briefly reports the synthesis, characterization and electronic absorption spectra, emission spectra, and paramagnetic resonance spectra of the title compounds.