The influence of laser parameters on arc behavior of laser-TIG double-side welding was investigated by utilizing CCD sensor and image processing methods. It was found that arc images had an obvious transformation from laser preheating to laser plasma ejected from the keyhole bottom, resulting in the phenomena of arc column convergence and arc root constriction. The attraction phenomenon of the laser and the arc is also found in laser-TIG double-side welding. More noteworthy is that the behavior of arc attraction or constriction became much obvious at a lower current or laser plasma ejected from the keyhole bottom. The decrease in arc voltage had a certain relation with the improvement of arc stability.