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该文总结了氟硅油的制备方法,包括硅氢加成法、水解法、开环聚合法,并讨论了分子结构对性能的影响,包括氟硅油多种界面功能的作用机理、氟-硅协同效应等。此外,该文还综述了氟硅油作为润滑剂、消泡剂、整理剂、超疏水材料的研究应用现状。氟硅油应用过程中,以有机磷化合物、硅醇铁等为添加剂能有效地提升氟硅油的抗剪切性、抗氧化性;在分子链中引入聚醚或氨基等制备共改性硅油,能够有效地提升氟硅油的表面性能。最后,对于氟硅油的发展方向和应用前景进行了展望。
This paper summarizes the preparation of fluorosilicone oil, including hydrosilylation, hydrolysis and ring-opening polymerization, and discusses the influence of molecular structure on the performance, including the mechanism of the function of fluorosilicone oil, Effect and so on. In addition, the article also reviews the current research and application of fluorosilicone oil as a lubricant, defoamer, finishing agent and superhydrophobic materials. Fluorosilicone oil application process to organophosphorus compounds, such as silanized iron as an additive can effectively improve the shear resistance of fluorosilicone oil, anti-oxidation; the introduction of polyether or amino in the molecular chain of the preparation of modified silicone oil, can Effectively improve the surface properties of fluorosilicone oil. Finally, the prospect and prospect of fluorosilicone oil are prospected.